Phase Diagrams in Igneous Systems

by

Dave Bryon, Mike Atherton, Alan Boyle and John Wheeler
University of Liverpool

 

This interactive courseware module approaches the use and interpretation of phase diagrams using various igneous systems. It is designed for first or second year undergraduates.


The module comprises six sections accessed via this main menu



Description of the module

The module makes full use of multi-media techniques to explain phase diagrams, for example user interactions, animations and simulations. The relationship between phases in different spaces (T-X, P-X, X-X, texture) is demonstrated simultaneously on screen and this helps the user to understand a subject that is traditionally found difficult. In addition, the ability to rotate and view phase relations in three dimensional space has obvious advantages over standard two dimensional textbook diagrams.

The module occupies about 4Mb and consists of six separate units, each containing approximately 45 minutes of material. The user is encouraged to undertake the units in the order presented, working from unary systems through to the three component ternary systems. The module is constructed so that the examples used to demonstrate binary systems are also components of the ternary systems.





The diopside-anorthite system is used to demonstrate crystallisation pathways in binary systems




1. Introduction to phase diagrams

This unit introduces the user to phase diagrams and the Phase Rule with an explanation of systems, equilibrium, components, phases and variance (divariant, univariant and invariant). The significance of the slopes of phase boundaries is also discussed. The unary H2O system is used to illustrate these concepts.





The fosterite-silica system is used to recap on information studied in earlier units, and to introduce new concepts (e.g. intermediate compounds)




2. Binary systems with no solid-solution

The diopside-anorthite system This unit introduces the user to the terms liquidus, solidus and eutectic and provides a brief review of the Phase Rule. Equilibrium crystallisation and melting pathways for different compositions are discussed along with potential variation in textures. The Lever Rule is explained and its use in determining the amounts of phases present is demonstrated.

 

3. Binary systems with intermediate compounds

The forsterite-silica system This unit introduces intermediate compounds, the peritectic, congruent and incongruent melting and the effect of pressure on phase equilibria.





The binary systems studied in earlier units are used to show how more complex ternary diagrams are constructed




4. Binary systems with solid-solution

The anorthite-albite system The An-Ab system is used to introduce the terms solvus, exsolution and sub-solidus. The unit also explains partial and complete solid solution, equilibrium/fractional crystallisation and melting, and gives an example of the effect of water on phase equilibria.

 

5. Ternary systems with solid-solution

The diopside-albite-anorthite system This unit shows how ternary systems can be built up from binary systems, and demonstrates different ways of representing 3D information in 2D space. The Di-Ab-An system is used to introduce primary fields, liquidus surfaces, thermal contours and the cotectic. Representative equilibrium crystallisation pathways are demonstrated simultaneously on 3D block and triangular composition diagrams.





Crystallisation pathways in ternary systems are demonstrated simultaneously on triangular composition diagrams and 3D block diagrams




6. Ternary systems with intermediate compounds

The forsterite-anorthite-silica system In the final unit the Fo-An-Si system is used to revise concepts and terms introduced in unit 5, as well as introduce the ternary cotectic and pseudo-ternary systems. The unit also demonstrates the effect of intermediate compounds on equilibrium crystallisation pathways in ternary space.




Running the software

The different parts of the module are accessed via a main menu and navigation around the module is by means of buttons along the base of the screen.



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